From Missing Links to New Records: A Series of Novel Polychlorine Anions
نویسندگان
چکیده
Herein we report the synthesis and structural characterization of four novel polychloride compounds. The compounds [CCl(NMe2)2][Cl(Cl2)3] [NPr4][Cl(Cl2)4] have been obtained from reaction corresponding chloride salts with elemental chlorine at low temperature. They are missing links in series monoanions [Cl(Cl)n]? (n=1–6). Additionally, decamethylferrocene was studied yielding [Cp*2Fe]2[Cl20], which contains largest known [Cl20]2? to date, [Cp*2Fe][Cl(Cl2)4(HF)], is first example a polychloride-HF network stabilized by strong hydrogen halogen bonding. All characterized single-crystal X-ray diffraction, Raman spectroscopy quantum-chemical calculations.
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2021
ISSN: ['1434-1948', '1099-0682']
DOI: https://doi.org/10.1002/ejic.202001072